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海水的低频化学弛豫声吸收

SOUND ABSORPTION IN SEA WATER DUE TO LOW FREQUENCY CHEMICAL RELAXATIONS

  • 摘要: 用圆柱共振器法测量了三种混合水溶液的声吸收与pH值的依赖关系,溶液中每种化学成分的浓度均参照Lyman-Fleming人造海水配方中对应成分的浓度来选取。测量的频率为2.9和6.8kHz。温度为12.4℃。结果表明,在海水的pH值范围内,B(OH)3弛豫的弛豫频率与pH值没有明显依赖关系。另外由实验结果可以看出在B(OH)3/CO2/Ca/Mg/NaCl水溶液中还存在一个由MgHCO3+引起的低频弛豫,其弛频约为3.5kHz。文末列出了由本文测得的B(OH)3,MgCO3和MgHCO3+弛豫的弛豫参数。

     

    Abstract: The dependence of 2.9 and 6.8 kHz sound absorption on pH of the B(OH)3/CO2/Ca/ NaCl, B(OH)3/CO2/Ca/Mg/NaCl and Mg/CO2/Ca/NaCl systems has been measured using the cylindrical resonator method. Tht concentration of each constituent in these systems was equal to that in Lyman and Fleming sea water. Measurements were made at atmospheric pressure and 12.4℃. Results show that the B(OH)3 relaxation frequency is independent of pH for the pH range of the ocean. It seems clear that there is another low frequency relaxation due to MgHCO3+ in the B(OH)3/CO2/Ca/Mg/NaCl system. The MgHCO3+ relaxation frequency in this case has been found to be about 3.5 kHz. The measured relaxation parameters of the B(OH)3, MgCO3 and MgHCO3+ relaxations for various systems are given in table.

     

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